Can Smoking Materials Like Cigars and Cigarettes Ignite Lighter Fluid?

Jul 26 / M. Dixon Robin, IAAI-CFI
Background
Fire Investigators have recently benefitted from several presentations and papers examining the competency of cigarettes as an ignition source for gasoline. It is generally accepted that cigarettes are not a competent ignition source for gasoline. However, less is known about cigarettes and lighter fluid. A recent investigation brought to light the question as to whether a smoking material would be competent ignition source for igniting charcoal lighter fluid. The question is simple on its face, but it obviously involves context. There are numerous variables that could be considered in a test like this such as duration, distance from the fuel, etc. Because this was an initial test, every possible variable was not addressed. In this test we specifically used Expert Grill Lighter Fluid produced by Royal Oak Enterprises, and Cheyenne brand menthol “cigars” which resembled cigarettes in dimension and construction.

Previous Research and Characterization
The research in to cigarettes and ignition of gasoline has been well documented, particularly by ATF’s Fire Research Laboratory (FRL). As Jamie Lord reported in his FireCred blog post, “A Review of Cigarettes as Ignition Sources (Part 1)”:

Perhaps the easiest category to talk about is cigarette ignition of gasoline or other common flammable gasses and liquids. A 1996 paper by Holleyhead (1)  found that many of the most commonly-encountered substances, including methane and petrol vapor, were not ignited by a lighted cigarette. In the early 2000’s, the US Bureau of Alcohol, Tobacco, Firearms & Explosions did extensive work to validate these findings, much of which has been published by Geiman and Marcus (2), and show that out of 4500 instances of exposure of lit cigarettes to ignitable concentrations of gasoline vapors in air, none of them resulted in ignition. I’ve personally done this several hundred times with cigarettes, and perhaps 20-30 times with cigars and had the same result: no ignitions.

Notably, NFPA 921 does not specifically address the ability of cigarettes or cigars to ignite lighter fluid. Vytenis Babrauskas cited research in his book, the Ignition Handbook, on the relative inability of cigarettes to ignite various mixtures of flammable gases in air but does not cite any specific research regarding the ability of cigarettes or cigars to ignite lighter fluid (3). In addition, Kirk’s Fire Investigation 8th Edition cited several research efforts aimed at characterizing the ability of a lit cigarette to ignite gasoline vapors (these tests failed), but none of the cited research addressed the ignition of lighter fluid.

According to Kirk’s Fire Investigation, 8th Edition, there are some baseline measurements regarding cigarettes’ temperature and energy measurements:

• During a "puff" or "draw," surface (solid) temperatures at the edge of the glowing mass can reach 850°C to 900°C (1,560°F to 1,650°F).
• After a puff, the hottest part shifts to the center, reaching 775°C (1,427°F), while the ash at the edge drops to approximately 300°C (572°F).
• Tests have shown maximum cigarette temperatures ranging from 400°C (760°F) to 780°C (1,440°F).
• The heat release rate (HRR) for an average tobacco cigarette is low, around 5 W, highlighting the need for direct contact with fuel for ignition.

Kirk’s goes on to state that an oft looked at issue is the ability of cigarettes to ignite flammable liquids or gases. Repeated tests involving lighted cigarettes inserted into explosive gasoline vapor-air mixtures have consistently failed to cause ignition, even when the cigarette is puffed. This is due to very low oxygen levels and high carbon dioxide levels within the cigarette's combustion zone, along with the short residence time of airborne vapors and flame quenching effects. Only highly reactive substances like hydrogen, hydrogen sulfide, carbon disulfide, acetylene, ethylene oxide, phosphine, and diethyl ether are susceptible to cigarette ignition, while gasoline vapors and methane are not. However, if a cigarette or cigar is actually lit in a flammable atmosphere, it will cause an ignition or explosion.

Kirk’s also importantly notes that, “pipe and cigar smoking is not basically different in its fire potential from cigarettes.”(4)

The Lighter Fluid and Smoking Materials
The Safety Data Sheet (SDS) (5) for lighter fluid produced by Royal Oak Enterprises LLC, the company that manufactures Expert Grill Lighter Fluid (6). The data shows that the ingredients are proprietary, so we do not know what they specifically are, but that it has a boiling point of 320 F and a flashpoint of 102 F. The specific gravity is .777. A forensic laboratory that previously analyzed the brand of lighter fluid classified the fluid as a medium petroleum distillate.

The Testing
We utilized a bottle of Expert Grill Lighter Fluid, Cheyenne Menthol cigars, and cotton hand towels for the test. More specifically, we sought to test the hypothesis that smoking material was a competent ignition source for the Expert Grill Lighter Fluid when the liquid had been applied to an item made of fabric.

The Cheyenne Menthol cigars resembled a cigarette in size and dimension, but for purposes of this blog we will refer to them as cigars. An improvised, manual “puffer” was utilized to maintain a cherry on the cigar. It was a simple contraption formed by modifying a ketchup squirt bottle. When the lit smoking material is placed in the end of the bottle, and the bottle is squeezed, air is drawn across the cherry and the smoking material remains lit.

The test took place inside an enclosed workshop that contained no HVAC or fans.

The test was designed to determine whether the cigar was competent ignition source when either in contact with the liquid-soaked towel or in an area just above the liquid-soaked towel where vapors could be present and mixed with the atmosphere. For the tests, approximately 15ml of the Expert Grill Lighter Fluid was poured on a cotton towel and then a lit cigar was placed either directly on top of the towel or on a metal screen approximately 1” above the towel. The screen consisted of ½” x ½” openings. Tests were undertaken to see if ignition would occur and, if so, whether it occurred immediately, within one minute, or within five minutes. The hypothesis was further tested by placing a lit cigar at a small height above a pool of the liquid (without the towel) and then physically placed in the liquid. Despite all of these variables, in no instance did a cigar ignite the liquid or the towel. When we poured approximately 15ml of the liquid onto a cotton towel and applied a lighter to the area where the liquid was poured, ignition occurred immediately.  The chart following the photographs of the test set up synopsizes the results.
Test Results
These tests showed that no ignition of the lighter fluid occurred when the cigars were used as an ignition source, despite changing the variable of proximity and duration.  

References

 (1) Holleyhead, R., “Ignition of flammable gases and liquids by cigarettes: a review”, Science & Justice, Volume 36, Issue 4, October 1996, Pages 257-266, Elsevier, 1996.
 (2) Geiman, J. and Marcus, H., “The Propensity of Lit Cigarettes to Ignite Gasoline Vapors”, Fire Technology 50(6), January 2013.
 (3) The Ignition Handbook (p. 717) states, “It may be surprising to realize that cigarettes, puffed or smoldering, are unable to ignite most mixtures of flammable gases in air, at least in laboratory tests. Strese [footnote 316] measured a wide variety of gas/air mixtures to determine which ones could and which ones could not be ignited by cigarettes.” According to the test, ignition was obtained only for acetylene, carbon disulfide, ethylene oxide, diethyl ether, hydrogen, hydrogen sulfide, and phosphine. Babrauskas, V. (2003), Ignition Handbook, Fire Science Publishers.
(4) Icove, D. J. & Haynes, G., (2018). Kirk’s fire investigation (8th ed.). Pearson.
(5) The SDS is dated May 20, 2019 and can be viewed at ebdd0ff9-a0ed-4c37-8095-878853e81882.pdf (thdstatic.com)
(6) Royal Oak LLC is identified as the manufacturer of Expert Grill Lighter Fluid according to the California Air Resources Board (CARB), a government organization who is the lead agency for climate change programs and oversees all air pollution control efforts in California. A list of CARB certified charcoal lighter products can be found at: https://ww2.arb.ca.gov/sites/